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Partially finished compost and chopped leaves each make terrific mulch. Although neither looks as good as the common wood mulches, both will provide your plants with optimal nutrition. If you use leaves, make sure they are thoroughly chopped, otherwise matting will occur and moisture will not be able to get down to your plants.
Also, don't think that more is better in the case of mulch. With trees, especially, think "wider" not "higher". Avoid piling mulch up in a volcano formation around the trunks of trees and thinking it will help - it won't.
There are several online calculators that help you figure out how much mulch you'll need to buy, depending on your garden size. See the resources area below for a couple of helpful links. Generally, one cubic yard of mulch covers 108 square feet at 3" deep.