The Chemistry of Food, Part 2--Vitamins


© Linda Mamassian

Ascorbic acid
Vitamins are organic compounds that are essential, in small quantities in our food, for life and good health. They play important roles in many biochemical processes, but they are not used directly for energy or for the material of body tissues. (Minerals are also important in our diet. But minerals are just chemical elements, not organic molecules.)

The word "vitamine" was created in 1912 by biochemist Casimir Funk, who discovered vitamins. He believed that they were all amines (containing the —NH2 group) that were vital to health. Although these "vital amines" are all vital to our health, only some of them are actually amines.

There are two broad categories of vitamins. The fat-soluble vitamins (vitamins A, D, E, and K) are more soluble in fats, hydrocarbons, and nonpolar solvents than they are in water. The water-soluble vitamins include vitamin C (ascorbic acid) and the B complex of vitamins. The eight vitamins in the B complex are thiamine (B1), riboflavin (B2), pyridoxine (B6), cobalamin (B12), biotin, folic acid, niacin, and pantothenic acid.

Vitamin Structures and Functions

The table below shows the structures of these vitamins and describes their functions.

WATER-SOLUBLE
VITAMINS
STRUCTURE
(Note that water-soluble vitamins have polar molecules.)
FUNCTION
Ascorbic Acid
(Vitamin C)
Strong blood vessels, collagen maintenance, resistance to infection, and healthy gums
Biotin Carbohydrate, fat, and protein metabolism, formation of fatty acids, utilization of B vitamins
Cobalamin
(Vitamin B12)
Carbohydrate, fat, and protein metabolism, maintenance of nervous system, blood cell formation
Folic acid
Folate
Folacin
Red blood cell formation, protein metabolism, growth and cell division
Niacin
Nicotinic Acid
Carbohydrate, fat, and protein metabolism, health of digestive system, blood circulation, nerve function, appetite
Pantothenic Acid Convertion of nutrients into energy, vitamin utilization, nerve function
Pyridoxine
Pyridoxal
Pyridoxamine
(Vitamin B6)
Carbohydrate and protein metabolism, formation of antibodies, red blood cells, nerve function
Riboflavin
(Vitamin B2)
Carbohydrate, fat, and protein metabolism, needed for cell respiration, mucous membranes
Thiamine
(Vitamin B1)
Carbohydrate metabolism, appetite maintenance, nerve function, growth & muscle tone
FAT-SOLUBLE
VITAMINS
STRUCTURE
(Note that fat-soluble vitamins have nonpolar molecules.)
FUNCTION
Cholecalciferol
(Vitamin D3)
Calcium and phosphorus metabolism (bone and tooth formation)
Retinol
Carotene
Growth and repair of body tissue, immune functions, night vision
alpha-Tocopherol Protects cell membranes and red blood cells from oxidation, may be active in immune function
Vitamin KFormation of blood clotting agents and bone

Dietary Sources of Vitamins

Information on dietary sources for the various vitamins is listed in the table below.
 

WATER-SOLUBLE
VITAMINS
DIETARY SOURCE
Ascorbic Acid
(Vitamin C)
Fruits (especially citrus) and vegetables
BiotinVarious foods
Cobalamin
(Vitamin B12)
All foods of animal origin
Folic acid
Folate
Folacin
Meat, leafy green vegetables, citrus fruits and juices, legumes, and whole grain products 
Niacin
Nicotinic Acid
Meat, legumes, and grains
Pantothenic Acidvirtually all foods
Ascorbic acid
Biotin
Vitamin B12
Folic acid
Niacin
Pantothenic Acid
Vitamin B6
Riboflavin
Thiamine
Vitamin  D
Vitamin A
Vitamin E
Vitamin K
   

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